NOVEL FLUORIDE TRANSFER AND BENZYNE INSERTION UPON REACTION OF CLSI(MENCH(2)CH(2))(3)N WITH LIC6F5

Authors
WAN YJ VERKADE JG
Citation
Yj. Wan et Jg. Verkade, NOVEL FLUORIDE TRANSFER AND BENZYNE INSERTION UPON REACTION OF CLSI(MENCH(2)CH(2))(3)N WITH LIC6F5, Organometallics, 13(11), 1994, pp. 4164-4166
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
11
Year of publication
1994
Pages
4164 - 4166
Database
ISI
SICI code
0276-7333(1994)13:11<4164:NFTABI>2.0.ZU;2-6
Abstract
Whereas ClSi(HNCH2CH2)(3)N (1) reacts with LiC6F5 in the expected mann er to give C6F5Si(HNCH2CH2)(3)N (3), ClSi(MeNCH(2)CH(2))(3)N (2) gives a mixture of C6F5Si(MeNCH(2)CH(2))(3)N (4), the fluoride-transfer pro duct FSi(MeNCH(2)CH(2))(3)N (5), and the benzyne insertion. product C6 F5Si(o-C(6)F(4)NMeCH(2)CH(2))(MeNCH(2)CH(2))(2)N (6) in, the approxima te ratio of 1:2:1, respectively. The structures of 5 and 6, determined by X-ray means, are presented.