UNUSUAL REARRANGEMENT IN THE PHOTOCHEMICAL ADDITION OF BIS(ALKYLIDENE)DISILACYCLOBUTANES TO C-60

Authors
KUSUKAWA T KABE Y ERATA T NESTLER B ANDO W
Citation
T. Kusukawa et al., UNUSUAL REARRANGEMENT IN THE PHOTOCHEMICAL ADDITION OF BIS(ALKYLIDENE)DISILACYCLOBUTANES TO C-60, Organometallics, 13(11), 1994, pp. 4186-4188
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
11
Year of publication
1994
Pages
4186 - 4188
Database
ISI
SICI code
0276-7333(1994)13:11<4186:URITPA>2.0.ZU;2-U
Abstract
The photochemical reaction of bis(alkylidene)disilacyclobutanes 1a,b w ith C-60 afforded the stable 1:1 adducts 3a,b, resulting from an unexp ected rearrangement of the disilacyclobutane unit. The structures of 3 a,b were determined by spectroscopic methods, including Si-29-H-1 HMBC hetero nuclear shift correlation experiments.