BRIDGING BY ADSORBED POLYMERS BETWEEN 2 SURFACES

Citation
Jb. Avalos et al., BRIDGING BY ADSORBED POLYMERS BETWEEN 2 SURFACES, The Journal of chemical physics, 101(10), 1994, pp. 9181-9194
Citations number
25
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
101
Issue
10
Year of publication
1994
Pages
9181 - 9194
Database
ISI
SICI code
0021-9606(1994)101:10<9181:BBAPB2>2.0.ZU;2-R
Abstract
We analyze the adsorption of flexible polymers between two parallel pl ates separated a distance 2l. We consider a semidilute polymer solutio n in contact with the two adsorbing walls and describe the statistics of bridges and loops. A detailed mean-field calculation allows us to o btain the size and density of bridges in two regimes: l>xi and l<xi, w here xi is the bulk correlation length, as well as the size of loop an d train sequences. These results are compared with a scaling analysis performed in the spirit of the self-similar profile introduced by de G ennes.