Non-linear effects occurring in photothermal microscopes based on prin
ciple of photothermal radiometry are studied as a function of the lase
r power and of the modulation frequency. For stainless steel, a second
harmonic component of up to 11% of the fundamental amplitude is found
. Phase shifts of up to 20 degrees are observed as a function of the m
odulation frequency. The nonlinearity is mainly due to Stefan-Boltzman
n's law. The experimental results are in good agreement with a theoret
ical model based on the static and oscillating temperature distributio
n.