Literature data on trichloroethylene chemistry have been summarized. A
ddition reactions of inorganic and organic reagents to trichloroethyle
ne have been considered, cycloaddition reactions with trichloroethylen
e participation have been classified. Trichloroethylene reactions with
different nucleophiles resulting in substitution of 1 to 3 chlorine a
toms by nucleophilic residues have been systematized. Reactions of eli
mination and oxidation of trichloroethylene as well as aspect of pract
ical application of its derivatives have been considered. The analysis
carried out shows wide synthetic opportunities for polyfunctional org
anic substances of different classes to be prepared based on trichloro
ethylene.