Major performances have been achieved with organic materials to build
electro-optical components such as phase or amplitude modulators. But
the main bridle of their development is the unstability of the Pockels
effect caused by the relaxation of the poled molecular groups grafted
on a polymer matrix. We present here a method to overcome the disadva
ntage based on the synthesis of a new polymer family, which keeps a go
od electro-optic coefficient until 85-degrees-C without depletion at t
his temperature for a long time.