NITRITE-SELECTIVE ISE BASED ON URANYL SALOPHEN DERIVATIVES

Authors
WROBLEWSKI W BRZOZKA Z RUDKEVICH DM REINHOUDT DN
Citation
W. Wroblewski et al., NITRITE-SELECTIVE ISE BASED ON URANYL SALOPHEN DERIVATIVES, Sensors and actuators. B, Chemical, 37(3), 1996, pp. 151-155
Citations number
15
Categorie Soggetti
Electrochemistry,"Chemistry Analytical","Instument & Instrumentation
Journal title
Sensors and actuators. B, Chemical → ACNP
ISSN journal
09254005
Volume
37
Issue
3
Year of publication
1996
Pages
151 - 155
Database
ISI
SICI code
0925-4005(1996)37:3<151:NIBOUS>2.0.ZU;2-9
Abstract
Anion selectivities of membranes based on uranyl salophen derivatives with substituents at the 4-position are presented. Derivative 2 (with 4-nitro substituent) has been applied to design a nitrite-selective io n-selective electrode (ISE) that shows linear response in the range 1- 3 of pNO(2)(-) with a slope of 56.2 mV decade(-1). The highest selecti vity over other anions and optimum performance of the electrodes are o btained for membranes containing tridocecylmethylammonium chloride (TD MAC) at 10 mol% versus ionophore as an additive.