W. Svendsen et G. Osullivan, STATISTICS AND CHARACTERISTICS OF XUV TRANSITION ARRAYS FROM LASER-PRODUCED PLASMAS OF THE ELEMENTS TIN THROUGH IODINE, Physical review. A, 50(5), 1994, pp. 3710-3718
Spectra of laser-produced plasmas of the elements from tin to iodine c
ontain weak bands of quasicontinuum overlaid by weak emission lines in
the 70-120-Angstrom region. Multiconfiguration-Dirac-Fock calculation
s show that these features are consistent with theoretical spectra for
4d(N)-4d(N-1)(5f + 6p) transitions in a number of adjacent ion stages
which are predicted to produce unresolved transition arrays (UTA) in
this spectral region. Moreover, the calculations predict a gradual dec
rease of 4d-5f oscillator strength with increasing ionization up to th
e eleventh spectrum where Sigma gf(4d-5f)approximate to 0. However, in
clusion of configuration interaction effects between the 4d(9)nf level
s showed that 4d(9)4f and 4d(9)5f mixing shifts this minimum to the th
irteenth spectrum. The theoretical data were then parametrized within
the UTA formalism and the different order moments corresponding to wei
ghted mean energy, variance, and skewness coefficient evaluated.