We report angle-resolved studies of projectile L(2,3)-shell autoioniza
tion electron emission by bombarding a polycrystalline Al surface with
0.2-5-keV Ne+ ions. Several previously unresolved transition lines ha
ve been observed and assignment to Ne 2p(3)nln'l'n''l'' and Ne+ 2p (3)
nln'l' autoionizing states has been proposed. We found that the P-3 tr
iplet is the dominant configuration for the excited Ne 2p(4)3s(2) and
its relative population depends sensitively on both the primary ion en
ergy and incidence angle. Analysis of the electron spectra shows that
most excited Ne particles are backscattered from the surface and decay
in vacuum, rather than inside the solid.