M. Hiramatsu et Y. Kawakyu, MERCURY-SENSITIZED HYDROGEN RADICAL PHOTOETCHING OF HYDROGENATED AMORPHOUS-SILICON, JPN J A P 2, 35(12A), 1996, pp. 1547-1549
A study of the etching of hydrogenated amorphous silicon films has bee
n carried out by using hydrogen radical produced by mercury-photosensi
tization of hydrogen gas. There was found it be an incubation period b
efore etching began, and the incubation period depended on surface pre
treatment conditions. It can be explained that the variation in incuba
tion period strongly depend on unevenness of the a-Si:H surface. It ha
s also been found that the actual etching rate of undoped a-Si:H incre
ases with decreasing the substrate temperature. The authors consider t
hat surface reaction, that is, adsorption of hydrogen radical, is domi
nant in this etching process.