T. Takagi et al., ELASTIC-SCATTERING AND VIBRATIONAL-EXCITATION CROSS-SECTIONS FOR ELECTRON COLLISIONS WITH C2F6, Journal of physics. B, Atomic molecular and optical physics, 27(21), 1994, pp. 5389-5404
Absolute elastic cross sections for e-C2F6 collisions have been measur
ed for impact energies of 2 to 100 eV and scattering angles from 10 to
130 degrees. From these, the integrated and momentum transfer cross s
ections were obtained by extrapolation and numerical integration. Ener
gy loss spectra were measured for vibrational excitation. The vibratio
nal excitation functions show resonances at 4.3 eV and 8.5 eV. By deco
mposition of the loss spectra and symmetry analysis according to angul
ar correlation theory, the resonances have been assigned to a temporar
y trapping of the electrons in the a(2u) (4.3 eV) and e(u) (8.5 eV) an
tibonding orbitals of the molecule.