Molecular emission cavity analysis (MECA) is a chemiluminescence techn
ique in which molecular emissions are generated within a cavity that i
s introduced into a hydrogen diffusion flame. The hydrogen flame acts
as the environment of radicals, atoms and molecules which promote the
chemical reactions producing excited species and the cavity acts as th
e environment for stabilizing the emitting species. The principles, de
velopment and applications of MECA are outlined and future possibiliti
es are discussed.