A new model of silica's aggregation in rubber, the Hexagon-linking Mod
el, is proposed and tested in this study, using transmitting, scanning
and analytical electron microscopy. When wetted in rubber, silica ten
ds to accumulate, by way of hexagonal rings, differently from carbon b
lack; the ''wetted'' states can be controlled through mixing procedure
s. The experimental evidence that aggregation of silica (original size
of 20 nm) precedes to a final size of 63.8 nm, as compared to a theor
etical value of 60 nm, supports the theoretical model. The wetted fill
er structure can be controlled by the mixing process, and hence desire
d composite properties can be achieved.