A. Datta et al., INTERCALATION OF A RHODIUM CARBONYL INTO THE LAYERED VANADYL PHOSPHATE VOPO4-CENTER-DOT-2H2O AND ITS CATALYTIC ACTIVITY, Journal of physical chemistry, 98(46), 1994, pp. 11811-11813
Evidence for the intercalation of a rhodium carbonyl into the layered
vanadyl phosphate, VOPO4.2H2O has been provided from XRD, FTIR, and XP
S studies. The incorporated rhodium carbonyl has been found to exhibit
catalytic activity and shape selectivity in the hydrogenation of olef
inic substrates.