Tl. Thiem et al., FAST METAL-ATOM GENERATION BY LASER VAPORIZATION OF CU, ZN, AND NI COMPOUNDS, Journal of physical chemistry, 98(46), 1994, pp. 11931-11941
Fast metal atoms, generated when irradiating copper, zinc, and nickel
compounds with 10 ns, 532 nm laser pulses in high vacuum, are investig
ated. The metal-atom intensities are observed to be more than an order
of magnitude higher when irradiating compounds as opposed to the pure
metal samples. At laser power densities below 10(9) W cm(-2), the met
al-atom velocity distributions are generally well described by shifted
Maxwellian distributions. At laser power densities exceeding 10(9) W
cm(-2), the velocity distributions become distinctly non-Maxwellian fo
r most investigated systems. Very fast Rydberg atoms are observed at t
he highest laser power densities and are attributed to three-body reco
mbination collisions following plasma formation.