FAST METAL-ATOM GENERATION BY LASER VAPORIZATION OF CU, ZN, AND NI COMPOUNDS

Citation
Tl. Thiem et al., FAST METAL-ATOM GENERATION BY LASER VAPORIZATION OF CU, ZN, AND NI COMPOUNDS, Journal of physical chemistry, 98(46), 1994, pp. 11931-11941
Citations number
34
Categorie Soggetti
Chemistry Physical
ISSN journal
00223654
Volume
98
Issue
46
Year of publication
1994
Pages
11931 - 11941
Database
ISI
SICI code
0022-3654(1994)98:46<11931:FMGBLV>2.0.ZU;2-S
Abstract
Fast metal atoms, generated when irradiating copper, zinc, and nickel compounds with 10 ns, 532 nm laser pulses in high vacuum, are investig ated. The metal-atom intensities are observed to be more than an order of magnitude higher when irradiating compounds as opposed to the pure metal samples. At laser power densities below 10(9) W cm(-2), the met al-atom velocity distributions are generally well described by shifted Maxwellian distributions. At laser power densities exceeding 10(9) W cm(-2), the velocity distributions become distinctly non-Maxwellian fo r most investigated systems. Very fast Rydberg atoms are observed at t he highest laser power densities and are attributed to three-body reco mbination collisions following plasma formation.