A. Roy et al., ORIGIN OF VISIBLE PHOTOLUMINESCENCE FROM POROUS SILICON AS STUDIED BYRAMAN-SPECTROSCOPY, Bulletin of Materials Science, 17(5), 1994, pp. 513-522
In this paper we discuss the different models proposed to explain the
visible luminescence in porous silicon (PS). We review our recent phot
oluminescence and Raman studies on PS as a function of different prepa
ration conditions and isochronal thermal annealing. Our results can be
explained by a hybrid model which incorporates both nanostructures fo
r quantum confinement and silicon complexes (such as SiHx, and siloxen
e) and defects at Si/SiO2, interfaces as luminescent centres.