Ne. Smeck et al., GENESIS AND NATIVE PHOSPHORUS DISTRIBUTION IN SOME PALEXERALFS OF SOUTHERN SPAIN, Soil Science Society of America journal, 58(6), 1994, pp. 1718-1723
Although deeply weathered soils are common on stable landscapes in Med
iterranean regions, little information exists regarding the quantities
and depth-distributions of native P forms in such soils. The objectiv
e of this investigation was to gather such information to determine th
e P status of Palexeralfs representative of southern Spain and to eval
uate the applicability of current models and paradigms for describing
pedogenic P transformations in such soils. Base saturation, clay distr
ibution, absence of primary carbonates, distribution of secondary carb
onates, extent of rubification, and properties of Fe (hydr)oxides all
indicate that the Palexeralfs are polygenetic. Yellowish-red lower sol
a are considered relicts attributable to deep leaching and weathering
during Pleistocene pluvial periods, whereas pedogenesis is active in u
pper yellowish-brown B horizons. Low total and labile P contents and t
he dominance of reductant-soluble and organic P fractions throughout e
ntire >3-m sola indicate that soil P distribution attained a terminal
steady state during the paleo-climatic regime and has been little affe
cted during the current semiarid climate. Although organic P (P-o) is
a major component of total P, stabilization of P-o by Fe (hydr)oxides
restricts P, mineralization and fosters the labile P deficient state o
f these soils.