R. Sykes et al., A PLANT-TISSUE ORIGIN FOR ULMINITE-A AND ULMINITE-B IN SASKATCHEWAN LIGNITES AND IMPLICATIONS FOR R(O), Energy & fuels, 8(6), 1994, pp. 1402-1416
This paper describes the petrography and organic geochemistry of Taxod
iaceae wood and bark tissues within Paleocene lignites of southern Sas
katchewan, Canada. The wood (secondary xylem) tissues are dominated by
ulminite, which fluoresces and is solely low-reflecting (dark) variet
y A. R(0) values are from 0.20 to 0.22%. The wood tissues are relative
ly hydrogen-rich and oxygen-poor, have depressed T-max values (374-380
degrees C), and are rich in methoxyphenol compounds. The bark tissues
are more heterogeneous in maceral and tissue compositions. They are d
ominated by interlayered cork (periderm) and ''A/B'' (secondary phloem
) tissues, the latter consisting of an intimate association of ulminit
e A and high-reflecting (light) ulminite B. R(0) values are from 0.24
to 0.27% for ulminite A and 0.36 to 0.44% for ulminite B. The bark tis
sues are relatively hydrogen-poor and oxygen-rich and have higher T-ma
x values (403-418 degrees C), and phenols are the dominant compounds.
The study provides unequivocal evidence of a plant tissue origin for t
he A (dark) and B (light) varieties of humotelinite macerals and revea
ls fundamental problems in the A vs B classification. The existence of
the humotelinite A and B varieties has significant implications for t
he use of R(0) as a rank parameter, and these implications are discuss
ed.