THE HYDROXYLATION OF GLOBULOL AND 7-EPIGLOBULOL BY CEPHALOSPORIUM-APHIDICOLA

Authors
HANSON JR HITCHCOCK PB MANICKAVASAGAR R
Citation
Jr. Hanson et al., THE HYDROXYLATION OF GLOBULOL AND 7-EPIGLOBULOL BY CEPHALOSPORIUM-APHIDICOLA, Phytochemistry, 37(4), 1994, pp. 1023-1025
Citations number
9
Categorie Soggetti
Plant Sciences
Journal title
Phytochemistry → ACNP
ISSN journal
00319422
Volume
37
Issue
4
Year of publication
1994
Pages
1023 - 1025
Database
ISI
SICI code
0031-9422(1994)37:4<1023:THOGA7>2.0.ZU;2-9
Abstract
Globulol and 7-epiglobulol were shown to be hydroxylated by Cephalospo rium aphidicola on one (C-14) of the methyl groups geminal to the cycl opropane ring in 48.5 and 56% yield, respectively. The significance of this hydroxylation adjacent to a cyclopropane ring is noted.