Hd. Goldberg et al., SCREEN PRINTING - A TECHNOLOGY FOR THE BATCH FABRICATION OF INTEGRATED CHEMICAL-SENSOR ARRAYS, Sensors and actuators. B, Chemical, 21(3), 1994, pp. 171-183
The commercialization of integrated chemical sensors has been slowed b
y the difficulty of device encapsulation and membrane application. For
reasons of both cost and reproducibility, the sensor-specific structu
res should be mass fabricated, as are the microelectronics. The challe
nge lies in merging the standard semiconductor process sequence with t
he non-standard steps used to form the transducers. We demonstrate tha
t screen printing can be used to partition the fabrication into two di
stinct sequences, semiconductor processing and sensor-specific steps.
This simplifies process development and evolution, and makes semicondu
ctor foundry services available for manufacturing sensors. After conve
ntional semiconductor processing, our wafers have silver epoxy contact
s screen printed on the aluminum sensor pads; the silver forms a stabl
e chemical interface to the membranes, and the epoxy makes a strong ph
ysical bond to them. Next, the polymeric membranes are applied and pat
terned with screen printing. Membranes of different compositions can b
e deposited on the various sites of a multisensor chip by simply repea
ting the screen print/cure cycle. We show that the electrochemical per
formance of mass-fabricated passive and active sensor arrays is compar
able to that of conventional liquid-junction ion-selective electrodes.