THE ENTROPY TERM IN ISODESMIC, ASSOCIATION, AND CONFORMATIONAL EQUILIBRATION REACTIONS

Authors
HYMAN AS LADON LH LIEBMAN JF
Citation
As. Hyman et al., THE ENTROPY TERM IN ISODESMIC, ASSOCIATION, AND CONFORMATIONAL EQUILIBRATION REACTIONS, Structural chemistry, 5(6), 1994, pp. 399-401
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Structural chemistry → ACNP
ISSN journal
10400400
Volume
5
Issue
6
Year of publication
1994
Pages
399 - 401
Database
ISI
SICI code
1040-0400(1994)5:6<399:TETIIA>2.0.ZU;2-4
Abstract
Isodesmic reactions involving methyl, phenyl, and vinyl species are sh own to be accompanied by small entropy changes. In contrast, the ''ass ociation'' reaction of methane with vinyl species has a large entropy change that is quite well estimated by approximate translational entro py differences. The effect of neglecting multiple species on conformat ional equilibrium returns us to small but still predictable changes.