In the composite system carbon fibre/magnesium alloy the interface rea
ctivity was varied over a wide range by adding different amounts of th
e alloying element aluminium (alloys: AM20, AZ91) and by using carbon
fibres of different surface properties (fibres: M40J, T300J). The stru
cture and composition of interlayers in these composites down to the a
tomic scale as well as their effect on the mechanical properties were
studied systematically by the combination of high-voltage electron mic
roscopy, high-resolution electron microscopy, energy-dispersive X-ray
spectroscopy and electron energy-loss spectroscopy with scanning elect
ron microscope in situ bending tests, As resulting microstructure and
nanochemistry correlate with the micromechanical fracture behaviour of
the metal matrix composites, the interface reactivity can be used as
a parameter governing the composite properties, In addition to precipi
tates of aluminium carbide, strongly influencing the fracture behaviou
r, there are also graphitic carbon ribbons and layers of nanocrystalli
ne magnesium oxide at the fibre/matrix interface. Increasing the react
ivity of the composite system, three characteristic modes of fracture
behaviour are observed: single fibre pullout, bundle fracture (the opt
imum composite) and brittle failure.