ASYMMETRIC ALDOL REACTIONS OF CHIRAL IMIDAZOLIDINONE FISCHER CARBENE COMPLEXES

Authors
POWERS TS SHI Y WILSON KJ WULFF WD RHEINGOLD AL
Citation
Ts. Powers et al., ASYMMETRIC ALDOL REACTIONS OF CHIRAL IMIDAZOLIDINONE FISCHER CARBENE COMPLEXES, Journal of organic chemistry, 59(23), 1994, pp. 6882-6884
Citations number
40
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
59
Issue
23
Year of publication
1994
Pages
6882 - 6884
Database
ISI
SICI code
0022-3263(1994)59:23<6882:AAROCI>2.0.ZU;2-F
Abstract
Highly selective aldol reactions with a-unsubstituted enolates are des cribed for a new class of chiral carbene complexes derived from chiral imidazolidinones in which the position of the chiral center is specif ically defined by the chelation of the chiral auxilliary to the metal center.