OPTICAL-PROPERTIES OF LANGMUIR-BLODGETT-FILM OF HEMICYANINE CONTAINING THE RARE-EARTH COMPLEX ANION DY(BPMPHD)2-

Authors
WANG KZ HUANG CH XU GX ZHAO XS XIA XH WU NZ XU LG LI TK
Citation
Kz. Wang et al., OPTICAL-PROPERTIES OF LANGMUIR-BLODGETT-FILM OF HEMICYANINE CONTAINING THE RARE-EARTH COMPLEX ANION DY(BPMPHD)2-, Thin solid films, 252(2), 1994, pp. 139-144
Citations number
9
Categorie Soggetti
Physics, Applied","Material Science","Physics, Condensed Matter
Journal title
Thin solid films → ACNP
ISSN journal
00406090
Volume
252
Issue
2
Year of publication
1994
Pages
139 - 144
Database
ISI
SICI code
0040-6090(1994)252:2<139:OOLOHC>2.0.ZU;2-B
Abstract
cyl-4-(2-(4-dimethylaminophenyl)ethenyl)pyridinium yl-3'-methyl-5'-pyr azolone-4')hexanedionato-[1,5]) dysprosium(III) was synthesized. The m onolayers formed on a pure water subphase (pH 5.6, 18-degrees-C) were transferred onto hydrophilic quartz, calcium fluoride, and glass subst rates successively with a transfer ratio of around unity. From second- harmonic generation (SHG) experiments, the second-order molecular hype rpolarizability beta was evaluated to be about 4.8 x 10(-48) C m3 V-2. The results of UV-visible, IR and X-ray photoelectron spectroscopy of the Langmuir-Blodgett films are also reported.