REGIOSELECTIVE COUPLING REACTION OF ALLYLIC BARIUM REAGENTS WITH EPOXIDES

Authors
YASUE K YANAGISAWA A YAMAMOTO H
Citation
K. Yasue et al., REGIOSELECTIVE COUPLING REACTION OF ALLYLIC BARIUM REAGENTS WITH EPOXIDES, Bulletin of the Chemical Society of Japan, 70(2), 1997, pp. 493-497
Citations number
43
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
70
Issue
2
Year of publication
1997
Pages
493 - 497
Database
ISI
SICI code
0009-2673(1997)70:2<493:RCROAB>2.0.ZU;2-F
Abstract
The regioselective coupling reaction of epoxides with allylic barium r eagents was achieved. All reactions resulted in high yields with remar kable ct-selectivities. 2-Propynylbarium reagent afforded exclusively the corresponding acetylenic alcohol.