The redistribution of Ga in amorphous silicon (a-Si) in the temperatur
e range of 560-830 K by means of medium-energy ion scattering has been
studied. During the initial 10 s of the annealing the diffusivity sho
ws a transient behavior that is attributed to the change in the relaxa
tion state of the amorphous matrix. From 560 to 830 K the diffusivity
during relaxation is enhanced by seven to two orders of magnitude comp
ared to the value for bulk a-Si. Possible models that show the observe
d transient diffusion behavior are discussed.