Energy-extended photoelectron holography has been applied for the firs
t time to image surface structure using intrinsic surface core-level s
hifts. The Ge(111)-c(2 x 8) 3d core level exhibits a surface component
shifted by 0.8 eV relative to the bulk. Angle-resolved photoemission
from this so-called S2 component shows intensity oscillations as a fun
ction of photon energy. Inversion of the data collected at many emissi
on angles yields a three-dimensional image of the nearby atoms, showin
g conclusively that the S2 emission is due to adatoms bonded in T-4 si
tes.