USE OF HETEROMETAL COMBINATIONS TO CONSTRUCT VERY BARGE RING FRAMEWORKS - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE 36-MEMBERED RINGCOMPOUND 4-PICOLYLPYRROLIDIN-2-ONE)(4)(NCS)(2)(NO3)(3))(N)]
Dml. Goodgame et al., USE OF HETEROMETAL COMBINATIONS TO CONSTRUCT VERY BARGE RING FRAMEWORKS - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE 36-MEMBERED RINGCOMPOUND 4-PICOLYLPYRROLIDIN-2-ONE)(4)(NCS)(2)(NO3)(3))(N)], Journal of the Chemical Society, Chemical Communications, (22), 1994, pp. 2605-2606
X-Ray diffraction studies on the complex [{NiNd(PPO)(4)(NCS)(2)(NO3)(3
)}n] (PPO = 4-picolylpyrrolidin-2-one) show that the PPO ligands conne
ct the Ni and Nd centres into sheets of 36-membered rings; the structu
re of [CoCl2(PPO)(4)] is also described.