EASILY REVERSIBLE IONIC FRAGMENTATION OF A TETRAHEDRAL UNSATURATED RHENIUM CLUSTER, A REAPPRAISAL OF THE REACTION OF [RE-4(MU(3)-H)(4)(CO)(12)] WITH METHANOL

Authors
BERINGHELLI T DALFONSO G
Citation
T. Beringhelli et G. Dalfonso, EASILY REVERSIBLE IONIC FRAGMENTATION OF A TETRAHEDRAL UNSATURATED RHENIUM CLUSTER, A REAPPRAISAL OF THE REACTION OF [RE-4(MU(3)-H)(4)(CO)(12)] WITH METHANOL, Journal of the Chemical Society, Chemical Communications, (22), 1994, pp. 2631-2632
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
22
Year of publication
1994
Pages
2631 - 2632
Database
ISI
SICI code
0022-4936(1994):22<2631:ERIFOA>2.0.ZU;2-O
Abstract
The unsaturated tetrahedral cluster [Re-4(mu(3)-H)(4)(CO)(12)] in the presence of weak donor molecules L, like methanol or acetone, reversib ly fragments to unsaturated triangular cluster anions and to mononucle ar cations, probably via spiked-triangular [Re-4(mu-H)(4)(CO)(12)L(4)] intermediates.