In a PK build-up fertilisation trial set up on calcareous humous sandy
soil, soil samples were taken build-up from rye fields to examine mag
nesium desorption using a fractionation technique. 10 mg fractions wer
e removed a five-minute intervals from a soil column set up in a Schac
htschabel tube using a peristaltic pump to maintain a constant (2 ml/m
in) rate of liquid flow, with identical volumes of liquid being introd
uced and removed and with a minimum of mixing. The soil samples were t
aken from the ploughed layer on ten occasion during the vegetation per
iod. The results can be summarised as follows: the quantity of availab
le KCl-soluble magnesium rose as the result of N, P and K fertilisatio
n. At higher rates of NPK there was a relative decrease compared with
the other treatments (Table 1); in an aqueous solution the desorbed Mg
content increased significantly in the N, NP, NK and NPK treatments o
ver all the samples compared with the control (Table 2); even in the f
irst fraction the intensity of magnesium desorption was very great, af
ter five minutes more than half the total amount desorbed over the 25-
minute period was already in solution (Table 2); the seasonal dynamics
of aqueous desorption could be statistically proved, maxima were meas
ured in early spring when the first soil sample were taken. A decrease
was generally observed during the later stages of vegetation. Minima
were found in summer, in samples taken in June (Table 3); on this sand
y soil magnesium rapidly enters the solution, thus becoming available
to plants; the calibration of this desorption process should be extend
ed to cover other soil types, using extraction agents more characteris
tic of soil suply levels.