X-RAY-ABSORPTION SPECTROSCOPIC STUDY OF THE ALPO4-5 - FERROCENE INCLUSION COMPOUND AND ITS THERMALLY DECOMPOSED PRODUCTS

Authors
LUND A NICHOLSON DG LAMBLE G BEAGLEY B
Citation
A. Lund et al., X-RAY-ABSORPTION SPECTROSCOPIC STUDY OF THE ALPO4-5 - FERROCENE INCLUSION COMPOUND AND ITS THERMALLY DECOMPOSED PRODUCTS, Journal of materials chemistry, 4(11), 1994, pp. 1723-1730
Citations number
48
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Journal of materials chemistry → ACNP
ISSN journal
09599428
Volume
4
Issue
11
Year of publication
1994
Pages
1723 - 1730
Database
ISI
SICI code
0959-9428(1994)4:11<1723:XSSOTA>2.0.ZU;2-9
Abstract
The synthesis and decomposition of an inclusion compound, AlPO4:Fe(C5H 5)2 is reported. This, and the decomposition products have been charac terised by extended X-ray absorption fine structure spectroscopy. The clustering of iron atoms either through Fe-Fe or Fe-O-Fe interactions is shown to be absent. Instead, Fe(III) is sited within the double 6-r ings of the 12-ring system. A model for distortions of the local latti ce about Fe(III) is proposed.