Ml. Frezzotti et al., MELT AND FLUID INCLUSIONS IN DUNITE XENOLITHS FROM LA GOMERA, CANARY-ISLANDS - TRACKING THE MANTLE METASOMATIC FLUIDS, European journal of mineralogy, 6(6), 1994, pp. 805-817
Composite xenoliths in alkali-basaltic lavas on La Gomera (Canary Isla
nds) consist of clinopyroxene-spinel-dunites cut by 3-mm to 2-cm wide
clinopyroxenite veins. The xenoliths are crosscut by a complex system
of mainly intracrystalline late veinlets, filled by microcrystalline a
ggregates and glass remnants. Two different types of fluid and melt in
clusions occur. Type 1: primary glass inclusions + CO2 fluid inclusion
s; these contain Cr-spinel and diopside daughter minerals, composition
ally similar to those in dunite. CO2 inclusions (L + V at room tempera
ture) have glass rims (10-30 % of the volume), and are always re-equil
ibrated. Type 1 inclusions are remnants of the magma from which the du
nites were formed. Type 2: secondary silicate glass inclusions and mix
ed silicate glass + carbonate inclusions, occurring together with reeq
uilibrated CO2 inclusions along fractures originating from a complex n
etwork of late veinlets. Melt inclusions contain a silicate glass whic
h may include a spherical carbonate droplet. The glass has an ultramaf
ic composition (MgO: 24-38 wt.%, FeO: 5-18 wt.% and SiO2: 33-46 wt.%).
A high volatile content (H2O + CO2) is suggested by very low oxide to
tals (approximate to 85 wt. %) and by high Cl contents (up to 3900 ppm
). Bulk analysis of late veinlets show similar compositions, but with
higher FeO/MgO ratios. The carbonates are high-Mg calcite or dolomite;
the shape of the crystal and the poor crystallinity suggest that they
were derived from a carbonate melt (carbonatite). Associated CO2 incl
usions, always containing some magnetite, have low densities (0.56-0.1
9 g/cm(3)). We propose that the fracture-bound ultramafic glass + carb
onate inclusions and the CO2 inclusions associated with Type-2 represe
nt a trapping episode of a homogeneous, volatile-rich, CO2-saturated m
elt which was present in the upper mantle during Canary Islands volcan
ism. This melt is responsible for mantle metasomatism, but apparently
distinct from the erupted lava.