Jf. Antona et al., FLUID-INCLUSION AND STABLE-ISOTOPE STUDIES OF GOLD TUNGSTEN BEARING HYDROTHERMAL DEPOSITS, SAUCELLE-BARRUECOPARDO AREA, SPAIN, European journal of mineralogy, 6(6), 1994, pp. 819-835
The Saucelle-Barruecopardo mineralized (Au-W) area is located in the n
orthwest of Salamanca province, Spain, within the Centroiberian zone (
the most internal part of Hercynian Cordillera System). The quartz vei
ns are spatially associated with the Barruecopardo granite, a syntecto
nic two-mica alkaline granite. The granite crosscuts regional metamorp
hic isograds and estimates of its emplacement age range from 311 to 32
6 M.a. Gold-tungsten-bearing veins crosscut the Barruecopardo granite
and the surrounding country rocks. The vein mineralogy can be subdivid
ed into five paragenetic stages. Gold deposition is associated with st
age I (gold included in arsenopyrite) and stage II (gold in cracks in
arsenopyrite). Stage I muscovites are dated (K-Ar method) at 277.9 +/-
5.6 and 257.0 +/- 5 M.a. Two main different compositional types of pr
imary fluid inclusions were observed in quartz: type (1) CO2-H2O inclu
sions, and type (2) CO2-rich inclusions. Type 1 and type 2 inclusions
are related to stage-I gold deposition and are thought to represent im
miscible fluids because they are primary and the homogenization temper
atures for both types (H2O-rich and CO2-rich) are in the same range, w
ith a maximum homogenization temperature of 428 degrees C. The calcula
ted temperature of immiscibility ranges from 355 to 435 degrees C and
pressures from 1400 to 2100 bars. delta(34)S arsenopyrite values sugge
st a constant source of sulphur with values close to O per mil. Calcul
ated delta D-fluid is values are all quite D-enriched, but show signif
icant Variability (-32 to -2 parts per thousand SMOW), whereas delta(1
8)O(fluid) values show small variation (from + 7 to + 10.3 parts per t
housand SMOW). These values for the fluids are consistent with interac
tion between magmatic fluids and metamorphic rocks (from 0.1 to 0.01 f
luid/rock ratios). The most likely mechanism for stage-I gold depositi
on is the loss of H2S during fluid immiscibility.