H. Dong et Aw. Thompson, EFFECTS OF HYDROGEN ON THERMALLY ACTIVATED DISLOCATION-MOTION IN IRON, Materials science & engineering. A, Structural materials: properties, microstructure and processing, 188(1-2), 1994, pp. 43-49
In a study of decarburized Armco iron and an Fe-0.17wt.%Ti alloy, ther
mal activation parameters such as m and A* were measured, in both the
presence and the absence of dissolved hydrogen. It was found that hyd
rogen did not significantly alter the thermal activation parameters. S
ince it is accepted that thermally activated dislocation motion in iro
n is controlled by Peierls-Nabarro barriers at low temperatures, this
finding means that hydrogen predominantly affects the now stress of ir
on through its interaction with other solutes such as carbon and titan
ium. This is consistent with fundamental deformation studies on iron a
s well as with previous work on hydrogen effects in iron.