INFRARED-SPECTRUM OF MATRIX-ISOLATED HEXAMETHYLENETETRAMINE IN AR ANDH2O AT CRYOGENIC TEMPERATURES

Authors
BERNSTEIN MP SANDFORD SA ALLAMANDOLA LJ CHANG S
Citation
Mp. Bernstein et al., INFRARED-SPECTRUM OF MATRIX-ISOLATED HEXAMETHYLENETETRAMINE IN AR ANDH2O AT CRYOGENIC TEMPERATURES, Journal of physical chemistry, 98(47), 1994, pp. 12206-12210
Citations number
41
Categorie Soggetti
Chemistry Physical
Journal title
Journal of physical chemistry → ACNP
ISSN journal
00223654
Volume
98
Issue
47
Year of publication
1994
Pages
12206 - 12210
Database
ISI
SICI code
0022-3654(1994)98:47<12206:IOMHIA>2.0.ZU;2-V
Abstract
The infrared specta of hexamethylenetetramine (HMT) isolated in an arg on matrix at 12 K, frozen in H2O at temperatures from 12 to 200 K, and as a pure solid, are reported. The results of ultraviolet photolysis of matrix-isolated HMT and HMT frozen in H2O ice are also presented, a nd implications for infrared astronomy and astrochemistry are discusse d. Furthermore, a simple technique for incorporating large nonvolatile organic molecules into a matrix is described.