M. Ichikawa et al., PICOSECOND REGULAR REFLECTION SPECTROSCOPIC STUDY ON ULTRAFAST PHOTOINDUCED HEAT-GENERATION IN COPPER PHTHALOCYANINE SOLID, Journal of physical chemistry, 98(47), 1994, pp. 12211-12214
The picosecond regular reflection spectroscopy system was developed an
d applied to a beta-copper phthalocyanine pellet. On the basis of tran
sient extinction coefficient change spectra obtained by Kramers-Kronig
transformation, excitation energy relaxation processes were analyzed.
A hot band due to a vibrationally excited state was confirmed to be t
he main transient species produced via exciton-exciton annihilation in
the picosecond time range.