SYNTHESIS AND PROPERTIES OF COPPER AND NICKEL-COMPLEXES OF THE GENERAL FORMULA (B11H11)(2)M(N-) - CRYSTAL-STRUCTURE OF [(N-BU)(4)N](3)[CU(B11H11)(2)]

Authors
KESTER JG KELLER D HUFFMAN JC BENEFIEL MA GEIGER WE ATWOOD C SIEDLE AR KORBA GA TODD LJ
Citation
Jg. Kester et al., SYNTHESIS AND PROPERTIES OF COPPER AND NICKEL-COMPLEXES OF THE GENERAL FORMULA (B11H11)(2)M(N-) - CRYSTAL-STRUCTURE OF [(N-BU)(4)N](3)[CU(B11H11)(2)], Inorganic chemistry, 33(24), 1994, pp. 5438-5442
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
33
Issue
24
Year of publication
1994
Pages
5438 - 5442
Database
ISI
SICI code
0020-1669(1994)33:24<5438:SAPOCA>2.0.ZU;2-D
Abstract
Reaction of Me(3)NH[B11H14] in aqueous NaOH with CuO or NiCl2 formed t he metallaborane anions Cu(B11H11)2(3-) Ni(B11H11)(2)(4-), respectivel y. NMR, XPS, and cyclic voltammetry results on some of these compounds are reported. A single-crystal X-ray structure determination of [N(n- Bu)(4)](3)[Cu(B11H11)(2)] has been completed (space group Pcnb, a = 43 .652(30) Angstrom, b = 23.221(13) Angstrom, c = 13.608(7) Angstrom, Z = 8).