COUPLING AND CARBONYLATION OF IODOAROMATICS AND TERMINAL ALKYNES OR ALKYNOLS CATALYZED BY A DIMERIC PALLADIUM HYDROXIDE

Authors
DELAUDE L MASDEU AM ALPER H
Citation
L. Delaude et al., COUPLING AND CARBONYLATION OF IODOAROMATICS AND TERMINAL ALKYNES OR ALKYNOLS CATALYZED BY A DIMERIC PALLADIUM HYDROXIDE, Synthesis, (11), 1994, pp. 1149-1151
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
11
Year of publication
1994
Pages
1149 - 1151
Database
ISI
SICI code
0039-7881(1994):11<1149:CACOIA>2.0.ZU;2-N
Abstract
The palladium(II) complex [(Ph(3)P)Pd(Ph)mu-OH)](2) is an effective ca talyst for the coupling and carbonylation of alkynes and iodoarenes to give acetylenic ketones in 63-94% yields. Acetylenic hydroxy ketones were formed using secondary or tertiary alkynols as reactants.