SIGMATROPIC ISOMERIZATIONS IN 2-AZA-ALLYLIC SYSTEMS .10. PROTOTROPIC AND CHLOROTROPIC REARRANGEMENTS IN FLUOROALKYL-SUBSTITUTED 1,3-DICHLORO-IMINES

Authors
ONYSKO PP KIM TV KISELEVA EI SINITSA AD
Citation
Pp. Onysko et al., SIGMATROPIC ISOMERIZATIONS IN 2-AZA-ALLYLIC SYSTEMS .10. PROTOTROPIC AND CHLOROTROPIC REARRANGEMENTS IN FLUOROALKYL-SUBSTITUTED 1,3-DICHLORO-IMINES, Journal of fluorine chemistry, 69(3), 1994, pp. 213-218
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
69
Issue
3
Year of publication
1994
Pages
213 - 218
Database
ISI
SICI code
0022-1139(1994)69:3<213:SII2S.>2.0.ZU;2-2
Abstract
The photochemical chlorination of N-benzylimidoyl chlorides RC(Cl)=NCH (2)Ph (R=CF3, CFCl2, C3F7, (t)Bu, Ar) results in RC(Cl)=NCH(Cl)Ph or i ts mixture with isomeric RCCl(2)N=CHPh depending on the nature of the substituent R. 1,3-Prototropic and 1,3-chlorotropic rearrangements in the chlorination products have been observed and investigated.