Our work describes how we obtain non-ionic tensides having perfluorina
ted hydrophobical chain by esterification of some perfluorocarboxylic
acids with polyethyleneglycols. The optimal esterification conditions
for perfluorocarboxylic acids, having 7,8 and 9 carbon atoms in their
molecule, with polyethyleneglycol of a 200 and 600 g/mol molecular wei
ght, respectively are described. The compounds obtained, are chemicall
y characterized by the hydroxyl and ester index. Some surface properti
es and the usage have been also established.