VIBRATIONAL-SPECTRA OF A SOLID-SOLUTION OF CADMIUM AND CALCIUM PYROPHOSPHATE

Authors
DEWAAL D HUTTER C
Citation
D. Dewaal et C. Hutter, VIBRATIONAL-SPECTRA OF A SOLID-SOLUTION OF CADMIUM AND CALCIUM PYROPHOSPHATE, Materials research bulletin, 29(11), 1994, pp. 1129-1135
Citations number
22
Categorie Soggetti
Material Science
Journal title
Materials research bulletin → ACNP
ISSN journal
00255408
Volume
29
Issue
11
Year of publication
1994
Pages
1129 - 1135
Database
ISI
SICI code
0025-5408(1994)29:11<1129:VOASOC>2.0.ZU;2-8
Abstract
Infrared and Raman spectra of the solid solution Cd1.25Ca0.75P2O7 are presented. The spectra of this phase are unique as a result of the C1 site for P2O7(4-) and the crystal structure of C1(1) which should not result in any splitting of the predicted vibrational modes for this io n with the eclipsed conformation, leaving it essentially free of inter ference arising due to crystal effects.