INTERMEDIATE SPECIES IN THE REACTION OF LOW-TEMPERATURE OXIDATION OF AMMONIA ON ZNO

Authors
SILCHENKOVA ON UKHARSKII AA MATYSHAK VA
Citation
On. Silchenkova et al., INTERMEDIATE SPECIES IN THE REACTION OF LOW-TEMPERATURE OXIDATION OF AMMONIA ON ZNO, Kinetics and catalysis, 35(5), 1994, pp. 708-712
Citations number
18
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
35
Issue
5
Year of publication
1994
Pages
708 - 712
Database
ISI
SICI code
0023-1584(1994)35:5<708:ISITRO>2.0.ZU;2-#
Abstract
Quantitative spectrokinetic measurements in steady-state and non-stead y-state regimes (simultaneous measurements of the reaction rate and co ncentration of surface compounds), show that a surface complex N2O(ads ) is the intermediate of the reaction of ammonia oxidation on ZnO. Dec omposition of this complex leads to the release of a reaction product (N2O) in the gas phase.