HETEROGENEOUS CATALYTIC ALLYLATION OF BICYCLO[2.2.1]HEPTA-2.5-DIENE BY ALLYL ACETATE

Authors
IVANOV AV MANULIK OS FLID VR BELOV AP
Citation
Av. Ivanov et al., HETEROGENEOUS CATALYTIC ALLYLATION OF BICYCLO[2.2.1]HEPTA-2.5-DIENE BY ALLYL ACETATE, Kinetics and catalysis, 35(5), 1994, pp. 716-717
Citations number
6
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
35
Issue
5
Year of publication
1994
Pages
716 - 717
Database
ISI
SICI code
0023-1584(1994)35:5<716:HCAOBB>2.0.ZU;2-E
Abstract
Heterogeneous catalytic allylation of bicyclo[2.2.1]hepta-2,5-diene (B CHD) by allyl acetate in the presence of the immobilized modified ally lnickel catalyst is accompanied by the hydride transfer and results in the adducts of BCHD and C3H4 fragment. Unlike the homogeneous process , 5-methylene-6-vinylbicyclo[2.2.1]heptene-2 is the predominant produc t, whose yield reaches 80 - 85%. The ratio of the adducts depends on t he temperature.