KINETIC CHARACTERISTICS OF THE REACTION OF MOLECULAR-OXYGEN WITH O- ANION-RADICALS ON THE MGO SURFACE

Authors
VOLODIN AM
Citation
Am. Volodin, KINETIC CHARACTERISTICS OF THE REACTION OF MOLECULAR-OXYGEN WITH O- ANION-RADICALS ON THE MGO SURFACE, Kinetics and catalysis, 35(5), 1994, pp. 718-721
Citations number
8
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
35
Issue
5
Year of publication
1994
Pages
718 - 721
Database
ISI
SICI code
0023-1584(1994)35:5<718:KCOTRO>2.0.ZU;2-#
Abstract
Thermodynamic and kinetic characteristics of the reaction O- + O2 reve rsible [O- . O2] involving anion-radicals O- (g perpendicular-to = 2.0 42, g parallel-to congruent-to g(e)) on the surface of MgO are studied . The heat of formation of [O- . O2] complexes is Q = (77 +/- 5) kJ/mo l, and the activation energy of their decomposition is E(a) = (84 +/- 7) kJ/mol.