While release of isoprene from the terrestrial biosphere is well estab
lished and known to influence the tropospheric concentrations of a num
ber of reactive species including ozone, very little is known of its p
roduction in the ocean and possible release to the marine boundary lay
er. Measurements reported here of low molecular weight trace gases pro
duced by a series of laboratory phytoplankton have shown that isoprene
is a major component. Though the results confirm that the oceans are
a potential source of isoprene to the atmosphere, it is not possible t
o extrapolate release rates from laboratory studies to the very differ
ent conditions under which marine plants grow naturally.