SYNTHESIS AND CHARACTERIZATION OF SOME MIXED-LIGAND COMPLEXES OF OXOVANADIUM(IV) WITH SOME AROMATIC-AMINES

Authors
MAURYA RC MISHRA DD DUBEY J WILLIAMS DH WORRELL JH
Citation
Rc. Maurya et al., SYNTHESIS AND CHARACTERIZATION OF SOME MIXED-LIGAND COMPLEXES OF OXOVANADIUM(IV) WITH SOME AROMATIC-AMINES, Synthesis and reactivity in inorganic and metal-organic chemistry, 24(10), 1994, pp. 1805-1816
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
24
Issue
10
Year of publication
1994
Pages
1805 - 1816
Database
ISI
SICI code
0094-5714(1994)24:10<1805:SACOSM>2.0.ZU;2-Y
Abstract
New mixed-ligand complexes of oxovanadium(IV) of the general formula [ VO(C2O4)(o-PDA)], where o-PDA = o-phenylenediamine, and [VO(C2O4)(L)(2 )], where L = N-methylaniline (NMA), N,N'-dimethylaniline (NNDMA), N,N '-diethylaniline (NNDEA), o-toluidine (o-TD), m-toLuidine (m-TD), o-an isidine (o-ANS), m-aniaidine (m-ANS), o-phenetidine (o-pD) or m-phenet idine (m-TD) have been synthesized by refluxing (oxalato) (diaquo)axov anadium(IV) with the said aromatic amines. The resulting complexes hav e been characterized on the basis of elemental analyses, vanadium dete rmination, molar conductances, magnetic measurements and infrared spec tral studies. Rectangular-pyramidal structures are likely for these co mplexes.