ULTRASOUND EFFECTS ON THE MN(III) - PROMOTED ADDITION OF AMIDOALKYL RADICALS TO OLEFINS

Authors
BOSMAN C DANNIBALE A RESTA S TROGOLO C
Citation
C. Bosman et al., ULTRASOUND EFFECTS ON THE MN(III) - PROMOTED ADDITION OF AMIDOALKYL RADICALS TO OLEFINS, Tetrahedron, 50(48), 1994, pp. 13847-13856
Citations number
4
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
48
Year of publication
1994
Pages
13847 - 13856
Database
ISI
SICI code
0040-4020(1994)50:48<13847:UEOTM->2.0.ZU;2-#
Abstract
Amidoalkyl radicals, generated from amides by Mn(OAc)(3) in acetic aci d react with phenyl substituted alkenes to generate five-membered lact ones or lactams. Ultrasound at ambient temperature significantly accel erates these single electron transfer reactions even when compared wit h conventional conditions under reflux or simple mechanical stirring. In some cases sonication leads to unusual products.