SELECTIVE DEPROTECTIVE METHOD USING PALLADIUM WATER-SOLUBLE CATALYSTS

Authors
LEMAIREAUDOIRE S SAVIGNAC M BLART E POURCELOT G GENET JP BERNARD JM
Citation
S. Lemaireaudoire et al., SELECTIVE DEPROTECTIVE METHOD USING PALLADIUM WATER-SOLUBLE CATALYSTS, Tetrahedron letters, 35(47), 1994, pp. 8783-8786
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
47
Year of publication
1994
Pages
8783 - 8786
Database
ISI
SICI code
0040-4039(1994)35:47<8783:SDMUPW>2.0.ZU;2-R
Abstract
Allylcarboxy and Allyloxycarbonyl groups can be removed without affect ing dimethylallylcarboxy and cinnamylcarboxy groups in the same molecu le. using Pd(0) water soluble catalyst prepared in situ, with diethyla mine as allyl scavenger. Homogeneous or biphasic media are suitable: t he yields of deprotection are quantitative.