Experimental investigations in a recirculating wind tunnel of the mech
anisms of formation of accretionary lapilli have demonstrated that gro
wt' is controlled by collision of liquid-coated particles, due to diff
erences in fall velocities, and binding as a result of surface tension
forces and secondary mineral growth. The liquids present on particle
surfaces in eruption plumes are acid solutions stable at much-less-tha
n-or-equal-to 100% relative humidity, from which secondary minerals, e
.g. calcium sulphate and sodium chloride, precipitate prior to impact
of accretionary lapilli with the ground. Concentric grain-size zones w
ithin accretionary lapilli build up due to differences in the supply o
f particular particle sizes during aggregate growth. Accretionary lapi
lli do not evolve by scavenging of particles by liquid drops followed
by evaporation - a process which, in wind tunnel experiments, generate
s horizontally layered hemispherical aggregates. Size analysis of part
icles in the wind tunnel air stream and particles adhering to growing
aggregates demonstrate that the aggregation coefficient is highly grai
n-size dependent. Theoretical simulation of accretionary lapilli growt
h in eruption plumes predicts maximum sizes in the range 0.7-20 mm for
ash cloud thicknesses of 0.5-10 km respectively.