A theoretical investigation of the hydrogen concentration distribution
in an aluminium workpiece during welding is presented. The driving fo
rce for hydrogen transport is thermal diffusion, whereby a diffusion c
urrent is brought about by temperature gradients. The sign of the resp
ective transport coefficient is negative for H in Al, which means that
hydrogen will accumulate in the heated regions. An analytical solutio
n is obtained under somewhat restrictive assumptions, which is complem
ented by a numerical solution allowing for more realistic input. Both
solutions agree qualitatively, yielding enrichment factors of two and
more for the cases studied. It is predicted that higher processing spe
eds will result in less enrichment. The significance of these results
for the weld quality is discussed.